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that in the gas phase the classical ion should be 5.2k cal mole(^ 1) more stable than the bridge protonated ethylene. Furthermore calculations along an idealised reaction coordinate representing trans formation between the two species have indicated the absence of an activation barrier thus suggesting the bridged ion to be the transition state for the scrambling of the hydrogen atoms of the ethyl cation. These results have been compared with mass spectrometric data. The advanced leader understands how to take action ba |
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